Product ID:CSM-1A DEGREASER
MSDS Date:01/05/1998
FSC:6850
NIIN:00N074017
Status Code:A
MSDS Number: CJYLF

MEASUREMENTS GROUP INC

RALEIGH, NC 27611
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 919-365-3800

Preparer: RL FRIDLEY

Cage: 88952

MEASUREMENTS GROUP INC

WENDELL, NC 27591 US

Telephone: 919-365-3800

Cage: 88952

ETHANE, 1,1-DICHLORO-1-FLUORO-;

CAS: 1717-00-6

RTECS: KI0997000

OSHA PEL N/K

ACGIH TLV: N/K

METHYL ALCOHOL; (METHANOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL 200 PPM, S

ACGIH TLV: 200PPM/250STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CARBON DIOXIDE (AS PROPELLANT ONLY)

CAS: 124-38-9

RTECS: FF6400000

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OR INGESTION MAY CAUSE
INTOXICATION OR ASPHYXIATION. SKIN CONTACT CAN CAUSE DEFATTING.
PERSONS WITH PRE-EXISTING RESPIRATORY OR HEART PROBLEMS MAY HAVE
THE CONDITION AGGRAVATED. INHALATION: AT LOW LEVELS OF
CONCENTRATION, INITIAL SYMPTOMS MAY INCLUDE HEADACHE, NAUSEA, LOSS
OF CONCENTRATION, AND IRRITATION. WITH HIGH EXPOSURE LEVELS,
CENTRAL NERVOUS SYSTEM DEPRESSION (INTOXICATION), CARD IAC
ARRYTHMIA, DECREASED BODY WEIGHT. PRODUCT VAPORS DISPLACE AIR CAN
CAUSE ASPHYXIATION, ESPECIALLY IN CONFINED SPACES. EYE CONTACT:
IRRITANT. LIQUID CONTACT WILL IRRITATE EYES AND MAY CAUSE CONJUNCT
IVITIS. (EFTS OF OVEREXP).
Effects of Overexposure:HLTH HAZ: SKIN CONTACT: DEFATTING OF THE SKIN
CAN CAUSE IRRITATION. NO ABSORPTION TOXICITY DATA IS AVAILABLE.
INGESTION: SIMILAR SYMPTOMS AS FOR INHALATION. DISCOMFORT DUE TO
THE VOLATILITY WOULD BE E XPECTED.
Medical Cond Aggravated by Exposure:PERSONS W/PREXISTING CHRONIC RESP
DISEASES/HEART DISORDER SHOULD REFRAIN FROM BREATHING EXCESSIVE
CARBON DIOXIDE. RECOVERY IS USUALLY RAPID FROM SHORT TERM
OVER-EXPOSURE (SUPDAT)

First Aid:INHAL: REMOVE VICTIM TO FRESH AIR. GIVE MOUTH-TO-MOUTH
RESUSCITATION IF BRTHG HAS STOPPED. GIVE OXYGEN AS NEC IF A
QUALIFIED OPERATOR IS AVAIL. DO NOT GIVE STIMULANTS OF ADRENALIN
(EPINEPHRINE). GET M ED ATTN IMMED. EYE: FLUSH W/LGE AMTS OF WATER
FOR AT LEAST 15 MIN, LIFTING EYELIDS PERIODICALLY UNTIL NO EVIDENCE
OF CHEM REMAINS. GET MED ATTN. SKIN: WASH PROMPTLY W/SOAP & WATER
FOR AT LEAST 15 MIN WHILE REMOVING CONTAMINATED CLOTHING & SHOES.
GET MED ATTN IMMEDIATELY. THOROUGHLY CLEAN CONTAMINATED CLOTHING &
SHOES BEFORE RE-USE OR DISCARD. INGEST: DO NOT INDUCE VOMITING. DO
NOT GIVE STIMULANTS. TAKE IMMED TO HOSPITAL OR PHYSICIAN.

Flash Point:NONE
Lower Limits:6.0%
Upper Limits:20.3%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY, OR
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . COOL FIRE-EXPOSED AEROSOL CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:CONCENTRATED VAPORS IN CONFINED OR POORLY
VENTILATED AREAS ARE IGNITABLE BY HIGH INTENSITY HEAT SOURCES OR
OPEN FLAMES. HIGH TEMPERATURES CAN CAUSE AEROSOLS TO FAIL
VIOLENTLY.

Spill Release Procedures:REMOVE OPEN FLAMES, HIGH-INTENSITY HEAT
SOURCES. WEARING PROTECTIVE NIOSH APPROVED RESPIRATORY EQUIPMENT
AND CLOTHING, TAKE UP SPILL ON INERT ABSORBENT MATERIAL AND
TRANSFER TO APPROVED WASTE CONTAINE RS. DO NOT FLUSH SPILLS OR
RESIDUE INTO SEWERS OR SURFACE WATER.

Handling and Storage Precautions:STORE AWAY FROM HEAT, FLAME,
INCOMPATIBLE AND OUT OF DIRECT SUNLIGHT, AT TEMPERATURES BELOW 120F
(49C). USE AWAY FROM HEAT, FLAME, HIGH-INTENSITY HEAT SOURCES.
Other Precautions:AVOID BREATHING VAPORS, AEROSOL SPRAYS AND MISTS.
AVOID SKIN CONTACT, EYE CONTACT, INGESTION. USE WITH ADEQUATE
VENTILATION. INTENTIONAL INHALATION ABUSE CAN BE HARMFUL OF FATAL.

Respiratory Protection:NONE REQUIRED WITH ADEQUATE VENTILATION. IF ANY
TLV IS EXCEEDED, WEAR NIOSH APPROVED SELF-CONTAINED POSITIVE
PRESSURE RESPIRATOR WHERE AIR CAN BE DISPLACED BY VAPORS AND IN
EMERGENCY SITUATIONS.
Ventilation:LOCAL EXHAUST/MECHANICAL: KEEP BELOW TLV.
Protective Gloves:POLYVINYL ALCOHOL OR NEOPRENE.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR AN IMPERVIOUS APRON OR OTHER PROTECTIVE CLOTHING AS
NEEDED TO PREVENT UNNECESSARY SKIN CONTACT WITH THE LIQUID OR ITS
SPRAYS DURING USE.
Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE PRACTICES. WASH
HANDS AFTER USE, BEFORE EATING, DRINKING OR SMOKING USING SOAP AND
WATER. NO EATING, DRINKING OR SMOKING AT POINT OF USE.
Supplemental Safety and Health
MED CNDTNS: WITH NO CONTINUING AFTER EFFECTS. LONG TERM OVER-EXPOSURE
MAY CAUSE COMA AND DEATH. VOLATILE ORGANIC COMPOUNDS: 1.0-3.5%.

Boiling Pt:=31.7C, 89.F
Vapor Pres:(MMHG): 4100
Vapor Density:4.1(AIR=1)
Spec Gravity:1.24 (H*2O=1)
Evaporation Rate & Reference:>1 (BUAC =1)
Solubility in Water:3.521% BY WEIGHT
Appearance and Odor:CLEAR, COLORLESS LIQUID, SLIGHT ETHEREAL/ALCOHOLIC
ODOR

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG ALKALIES AND ACIDS, REACTIVE EARTH METALS,
AND STRONG OXIDIZERS.
Stability Condition to Avoid:UNSTABLE AT TEMPERATURES EXCEEDING 207F
(97C) OR WITH FLAME CONTACT.
Hazardous Decomposition Products:WHEN THERMALLY DECOMPOSED, PRODUCES
HYDROFLUORIC ACIDS, CARBONYL HALIDES OR PHOSGENE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL ENVIRONMENTAL REGULATIONS. WASTE MAY BE RECLAIMED OR
INCINERATED BY FEDERALLY PERMITTED FACILITIES.

Toxicological Information:1,1-DICHLORO-1-FLUOROETHANE: OTHER: 500 PPM
TWA (AMERICAN INDUSTRIAL HYGIENE ASSOCIATION). METHAL: OSHA PEL:
200 PPM, ACGIH TLV: 260 MG/M3, OTHER 250 STEL, CARBON DIOXIDE: OSHA
PEL: 10000 PPM, ACGIH T LV: 18000 MG/M3, OTHER: 30000 STEL.

Transport Information:SHIPPING NAME: AEROSOLS, 20, NON-FLAMMABLE,
N.O.S. (HCFC 14LB). CLASS: 2.2. UN NUMBER: 1950.

SARA Title III Information:SECTION 313 SUPPLIER NOTIFICATION: THIS
PRODUCT CONTAINS A TOXIC CHEMICAL OR CHEMICALS (AS LISTED BELOW)
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 TITLE III OF
THE SUPERFUND AMENDMENT AND R EAUTHORIZATION ACT OF 1986 AND 40 CFR
PART 372. CAS NUMBER: 67-56-1. CHEMICAL NAME: METHYL ALCOHOL
(METHANOL) % BY WEIGHT: 1.0-3.5.
Federal Regulatory Information:TSCA NOTIFICATION: ALL COMPONENTS OF
THIS PRODUCT ARE LISTED IN THE TOXIC SUBSTANCE CONTROL ACT CHEMICAL
SUBSTANCE INVENTORY (TSCA).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.